postfix problem with talktalk?

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Hello,

I use my server to send mails to my googlemail account, containing various bits of info this works great using postfix.

Problem is I am trying to do the same for my brother and do not know why it is not working.

When sending mails I get the following error and the mail is not sent:

May 26 17:31:46 server postfix/pickup[3024]: 4D3B7B79CC: uid=0 from=<root>
May 26 17:31:46 server postfix/cleanup[3029]: 4D3B7B79CC: message-id=< 20070526163146.4D3B7B79CC@xxxxxxxxxxxxxxxxxx>
May 26 17:31:46 server postfix/qmgr[3025]: 4D3B7B79CC: from=< root@xxxxxxxxxxxxxxxxxx>, size=495, nrcpt=1 (queue active)
May 26 17:31:56 server postfix/smtp[3031]: 4D3B7B79CC: to=<pnward@xxxxxxxxxxxxxx>, relay=none, delay=10, delays= 0.38/0/10/0, dsn=4.4.3, status=deferred (Host or domain name not found. Name service error for name=googlemail.com type=MX: Host not found, try again)

On my server I get:
May 26 17:27:29 mythtv postfix/smtp[13482]: AB91A13F72A: to=< pnward@xxxxxxxxxxxxxx>, relay=gmail-smtp-in.l.google.com[66.249.93.27]:25, delay=1.1, delays=0.03/0.04/0.55/0.51, dsn=2.0.0, status=sent (250 2.0.0 OK 1180196902 a1si2615603ugf)

He is using my main.cf file so the only thing I can think of is talktalk block the mails from being sent.

How do I fix this so I can send mails to his email account?

Paul

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